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MINNESOTA DEPARTMENT OF HEALTH <br />WATER QUALITY PARAMETERS <br />VOLATILE ORGANIC CHEMICALS (VOCS) are a large group of low boiling point, carbon-containing, predomi­ <br />nantly manmade substances. VOC's are contained in a wide variety of industrial, cowmercial, and resi­ <br />dential products including: cleaners, degreasers, paints, solvents, inks, and petroleum distillates. <br />VOC's do not normally occur in groundwater. Their presence usually signifies contamination f”om <br />improper use, storage, disposal, spillage or leakage of solvents or petroleum products. V0C*s vary <br />widely in their toxicity and drinking water concentration standards. <br />NITRATE AND NITRITE NITROGEN is used as one of the principal indicators of water quality. Nitrate <br />is the stable form of nitrogen in oxygenated groundwater. Nitrite presents a particular health threat <br />to infants. Sources of nitrogen include: municipal and industrial wastes, landfill leachate, animal <br />and human wastes, nitrogen fertilizers, decomposition of organic matter and dissolution of nitrogen- <br />containing soil and rocks. Background concentrations* in Minnesota groundwaters range from less than <br />0.4 milligrams per liter (mg/l) to 140 ing/1 with a mean of 2.7 mg/1, A primary drinking water standard <br />of 10 mg/l has been established for pul'^r water supplies. <br />AltlONIA, a compound of nitrogen and hydrogen, is generally found In low concentrations In groundwater <br />due to oxidation to nitrate and adsorption to soil particles. High concentrations of ammonia may <br />represent oxygen depleted water or rapid introduction of ammonia fertilizers, animal or human wastes, <br />or leaching of solid wastes. <br />CHLORIDE is one of the major inorganic anions in water. Chloride is very soluble and will move through <br />groundwater with little attenuation. The presence of chloride in groundwater may be due to natural <br />salts in sods or rocks, or leaching of chemical fertilizers, solid wastes or highway deicing salts. <br />Background chloride concentrations in Minnesota groundwaters range from 0.3 mg/l to 490 mg/l, with <br />a mean of 19.2 mg/l. The secondary drinking water standard (recommended guideline) for public water <br />supplies is 250 mg/l. <br />SULPHATE occurs almost universally in groundwater. Rainfall may contain 10 mg/l or more sulphate. <br />Household wastes, including detergents, may add 10 mg/l or more sulphate to sewage. The usual source <br />in groundwater is naturally occurring sulphates of gypsum or anhydrite. Background concentrations <br />of sulphate in Minnesoti groundwaters range from 0.5 mg/l to 1300 mg/l with a mean of 72 mg/l. The <br />secondary drinking water standard for public water supplies is 250 mg/l. <br />IRON is a commonly found constituent in groundwaters, primarily derived fr^ weathering of soil and <br />rocks. High concentrations can be due to corrosive water or leaching of wastes. Background concen­ <br />trations in Minnesota groundwaters range from less than 0.03 mg/l to 46 mg/l with a mean of 1.3 mg/l. <br />The secondary drinking water standard for public water supplies is 0.3 mg/l. <br />SPECIFIC CONDUCTANCE is a measure of the ability of water to conduct an electric current. This ability <br />depends on the presence, concentration, and chemical state of ions. Wastewater and leachate typically <br />h##e high concentrations of dissolved material (ions) and therefore high specific conductance. Back­ <br />ground specific conductance in Minnesota groundwaters ranges from 50 to 2500 micromhos per centimeter <br />(pmho/cm) with a mean of 630 umho/cm. Specific conductance is often used to estimate total dissolved <br />solids (TOS) by multiplying specific conductance by .6. The secondary drinking water standard for <br />public water supplies is 500 mg/l TOS. <br />pH is a measure of the hydrogen ion activity of water. pM less than 7 represents acid conditions, <br />pH greater than 7 represents alkaline or basic conditions. Background pH levels in Minnesota ground- <br />waters range from 5.9 to 9.4 with a mean of 7.5. The secondary drinking water standard for public <br />water supplies iS 6.5 to 8.5. <br />•Background concentrations represent water quality values from 4|0 wells and springs sampled throughout <br />Minnesota in the Minnesota Pollution Control Agmey’s Ground W^trr Quality Moniforinq Program. <br />710 iM