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MINNESOTA DEPARTMENT OF HEALTH <br />WATER QUALITY PARAMETERS <br />VOLATILE ORGANIC CMEHICALS (VOC's) arc a large group of low boiling point, carbon-containing, predomi­ <br />nantly manmade substances. VOC's are contained in a wide variety of industrial, commercial, and resi­ <br />dential products including: cleaners, degreasers, paints, solvents, inks, and petroleum distillates. <br />VOC's do not normally occur in groundwater. Their presence usually signifies contamination from <br />improper use, storage, disposal, spillage or leakage cf solvents or petroleum products. VOC's vary <br />widely in their toxicity and drinking water concentration standards. <br />NITRATE ANO NITRITE NITROGEN is used as one of the principal indicators of water quality. Nitrate <br />is the stable foiTn of nitrogen in oxygenated groundwater. Nitrite presents a particular health threat <br />to infants. Sources of nitrogen include: municipal and industrial wastes, landfill leachate, animal <br />and human wastes, nitrogen fertilizers, decomposition of organic matter and dissolution of nitrogen- <br />containing soil and rocks. Background concentrations* in Minnesota groundwaters range from less than <br />0.4 milligrams per liter (mg/1) to 140 mg/1 with a mean of 2.7 mg/1. A primary drinking water standard <br />of 10 mg/1 has been established for public water supplies. <br />AfiNMIA, a compound of nitrogen and hydrogen, is generally found in low concentrations in groundwater <br />due to oxidation to nitrate and adsorption to soil pa*‘ticles. High concentrations of aanonia may <br />represent oxygen depleted water or rapid introduction of ammonia fertilizers, animal or human wastes, <br />or leaching of solid wastes. <br />CHLORIDE is one of the major inorganic anions in water. Chloride is very soluble and will move through <br />groundwater with little attenuation. The presence of chloride in groundwater may be due to natural <br />salts in soils or rocks, or leaching of chemical fertilizers, solid wastes or highway deicing salts. <br />Background chloride concentrations in Minnesota groundwaters range from 0.3 mg/1 to 490 mg/1, with <br />a mean of 19.2 mg/1. The secondary drinking water standard (recofimended guideline) for public water <br />supplies is 2S0 mg/1. <br />.SULPHATE occurs almost universally in groundwater. Rainfall may contain 10 mg/1 or more sulphate. <br />Household wastes, including detergents, may add 10 mg/1 or more sulphate to sewage. The usual source <br />in groundwater is naturally occurring sulphates of gypsum or anhydrite. Background concentrations <br />of sulphate in Minnesota groundwaters range from O.S mg/1 to 1300 rog/1 with a mean of 72 mg/1. The <br />secondary drinking water standard for public water supplies is 2S0 mg/1. <br />IRON is a commonly found constituent in groundwaters, primarily derived from weathering of soil and <br />rocks. High concentrations can be due to corrosive water or leaching of wastes. Background concen­ <br />trations in Minnesota groundwaters range f/om less than 0.03 mg/1 to 46 mg/1 with a mean of 1.3 mg/1. <br />The secondary drinking water standard for public water supplies is 0.3 mg/1. <br />SPECIFIC CONOUCTANCE is a measure of the ability of water to conduct an electric current. This ability <br />depends on the presence, concentration, and chemical state tC Wastewater and leachate typically <br />have high concentrations of dissolved material (ions) and high specific conductance. Back­ <br />ground specific conductance in Minnesota groundwaters rangi*’ SO to 2S00 micromhos per centimeter <br />(umho/cm) with a mean of 630 iimho/cm. Specific conductance is often us?d to estimate total dissolved <br />solids (TOS) by multiplying specific conductance by .6. The secondary drinking water standard for <br />public water supplies is SOO mg/1 TOS. <br />pH is a measure of the hydrogen ion activity of water. pH less than 7 represents acid conditions. <br />pH greater than 7 represents alkaline or basic conditions. Background pH levels in Minnesota ground- <br />waters range from 5.9 to 9.4 with a mean of 7.5. The secondary drinking water standard for public <br />water supplies is 6.5 to 8.5. <br />*Background concentrations represent water quality values from 413 wells and springs sampled throughout <br />Minnesota in the Minnesota Pollution Control Agency's Ground Walir Quality Monitoring Program. <br />MHI) 710 tM 19R6